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Metal Gear Solid
Tough question. Worth checking out, yes, but that's almost just for batshit insane story moments and sick boss fights/concepts.
Gameplay, has it held up? That's tougher. I think the controls for 2&3 especially show their age. They're very fiddly.
FWIW, I came to the series very late. Probably 2013ish on the release of The Legacy Collection for PS3.